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In this 2-part article series, we explore the various aspects of dissipation studies and how they are used in risk assessment. Part 1 was published in October and examined Aquatic Dissipation studies.
Today, we move away from water to take a closer look at Terrestrial Field Dissipation (TFD) studies. Unlike their wetter counterparts, Terrestrial Studies, as their name implies, focus on pesticide behavior under typical use conditions when a product is applied to the landscape. These studies help qualify and quantify where and what happens to active ingredients and their degradation products over time. While laboratory studies provide valuable data for specific individual processes, such as with leaching or microbial degradation, observations and results can differ when multiple processes, like drift, plant uptake, runoff, or volatilization, occur in parallel. If the differences are significant, they can potentially change the timing and magnitude of a chemical’s fate.
In the US, TFD studies are a key data requirement in two situations: the registration of new agrochemical products or when existing products seek changes to their labels such as rates and geographical application areas. To conduct these studies, entities must follow US Environmental Protection Agency (USEPA) and North American Free Trade Agreement (NAFTA) guidance (835.6100) along with Good Laboratory Practice Standards to ensure that quality data and testing are completed. This rule is in place so that comparisons to models of pesticide behaviors from laboratory studies can be confirmed.
Since TFD design and the parameters monitored and collected can vary, samples from soils in the field are typically taken over a 1-2 year period across a replicate block to determine the DT50, DT75 and DT90 field values for soil along with a representative half-life of each parent and major metabolite. Other critical...
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